Jul 14, 2017· Compounds of Cement cement compounds. About 9095% of a Portland cement is comprised of the four main cement minerals, which are C 3 S, C 2 S, C 3 A, and C 4 AF, with the remainder consisting of calcium sulphate, alkali sulphates, unreacted (free) CaO, MgO, and other minor constituents left over from the clinkering and grinding four cement minerals play very different roles in .